Jami and Tox are completely decentralized messaging systems.
They are not directly associated with "blockchain" buzzword as well so they have that going for them, too.
Jami uses git and TLS to implement E2E encrypted chats.[1] That doesn't sound all that secure to me. I'd feel much more comfortable using a fork of Signal with an onion router.
I don't get the prejudice some have against blockchains either. It's not even like this is Keybase where they shoehorned a crypto wallet into the app. They do have a wallet but it's a totally separate application. Session is purely a messenger and nothing else, you'd have no idea a blockchain was involved at any part of the backend if you weren't told about it.
I have played around with Tox and it's a cool project, but it's been in beta since 2014 and is not well optimised for mobile at all. I don't think it'll go very far personally.
https://jami.net/
https://tox.chat/